| Name | Character | Episodes |
|---|---|---|
| Richard Armitage | Claude Monet | 3 |
| Paloma Faith | Renoir's Model | 3 |
| James Lance | Bazille | 3 |
| Julian Glover | Claude Monet - older | 3 |
| Crispin Bonham-Carter | Ambroise Vollard | 3 |
| Anthony Calf | Emile Zola | 3 |
| Andrew Havill | Manet | 3 |
| Aden Gillett | Degas | 3 |
| Amanda Root | Alice Hoschede | 3 |
| Sebastian Armesto | Art Critic | 3 |
| Michael Culver | Cezanne's father | 3 |
| Charlie Condou | Renoir | 3 |