| Name | Character | Episodes |
|---|---|---|
| Beyoncé | Self - Awardee / Performer | 1 |
| Michael Herbig | Self - Presenter | 1 |
| Britney Spears | Self - Awardee (pre-taped appearence) | 1 |
| Ronan Keating | Self - Perfomer | 1 |
| Anke Engelke | Self - Presenter | 1 |
| Kelly Rowland | Self - Awardee / Performer | 1 |
| Ricky Martin | Self - Performer | 1 |
| Stefan Raab | Self - Awardee | 1 |
| Anastacia | Self - Performer | 1 |
| Michelle Williams | Self - Awardee / Performer | 1 |
| Joey Kelly | Self - Presenter | 1 |
| Craig David | Self - Awardee / Performer | 1 |
| Sandy Mölling | Self - Performer | 1 |